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Pd-catalyzed desulfonylative fluorination of electron-deficient (hetero)aryl sulfonyl fluorides

https://doi.org/10.1039/D5SC00912J

Hall, Jonathan R; Romer, Natalie P; Spiller, Taylor E; Sigman, Matthew S; Sanford, Melanie S (October 2025, Chemical Science)

Pd catalysis is used to convert electron-deficient (hetero)aryl sulfonyl fluorides to the corresponding (hetero)aryl fluorides with extrusion of SO₂.
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Free, publicly-accessible full text available October 15, 2026
Data Science Guided Multiobjective Optimization of a Stereoconvergent Nickel-Catalyzed Reduction of Enol Tosylates to Access Trisubstituted Alkenes

https://doi.org/10.1021/acscatal.4c00650

Romer, Natalie P.; Min, Daniel S.; Wang, Jason Y.; Walroth, Richard C.; Mack, Kyle A.; Sirois, Lauren E.; Gosselin, Francis; Zell, Daniel; Doyle, Abigail G.; Sigman, Matthew S. (April 2024, ACS Catalysis)

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